Passive Samplers for PPM-level Organic Vapors
A diffusion
barrier maintains sample uptake by molecular diffusion independent
of wind velocity. The sorbent is chosen to best collect the chemical
hazards of interest.
SKC Passive Samplers
SKC passive samplers
are small "badges" that collect organic vapors
without the use of a pump. Individual chemicals simply diffuse from
the atmosphere into the sampler at a fixed rate. SKC has scientifically
validated the sampling rate of the 575 Series passive samplers along
with other critical sampling parameters to meet OSHA/ASTM/ANSI requirements.
SKC 575 Series Passive Samplers are identified as a viable alternative
to active sampling in seven OSHA methods.
- Highly accurate and reliable
-
Proven performers in the laboratory and in the field
- Save time and money
-
Collect most compounds with one sampler for up to a full 8-hour workshift
eliminating multiple trips to the worksite
- One sampler + one analysis = money saved
- Economical solvent desorption and GC analysis
- Reusable badge housing with transferable sorbent available
- Variety of samplers available
- Only SKC offers a choice of sorbents to better target specific contaminants
- Proper sorbent selection means no reverse diffusion
- Superior collection efficiency
- SKC sorbents have a larger surface area for higher capacities
- Samplers contain a minimum of 300 mg of sorbent — much
more than other brands
- Sampling flexibility
- Validated for short-term and 8-hour sampling
- Suitable for 24-hour indoor air sampling for some compounds
- Proven results
- So easy to use!
- No pump or training required
- Meet ASTM D6246-98 and ANSI/ISEA 104-1998 standards
- Identified as viable alternative to active sampling
in seven OSHA methods
Full-shift Sampling with Only ONE Badge
SKC 575 Series Passive Samplers are validated for a full 8 hours, that's TWICE the
limit value! This assures the integrity of the sampler, so you only
need ONE badge to get a true 8-hour TWA!
Using an SKC Passive Sampler is as easy as 1, 2, 3
| 1. |
Remove sampler from pouch. |
|
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| 2. |
Record start time, remove
cap, and attach to a worker or at a location. |
|
|
| 3. |
After sampling,
cap sampler and record stop time. Send the sampler
to an accredited laboratory for analysis. |
|
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575 Series Passive Samplers Validated to
NIOSH Protocol 1
For compliance sampling, it is recommended that only passive samplers with
full or bi-level validation be used. Passive samplers with lower levels of
validation may be used only if verified by validated sorbent sample tube methods.
Validation
Passive sampling is quite different from active sampling with sorbent
tubes. With this fact in mind, NIOSH established validation protocols
for evaluating the performance of passive samplers. 1 Protocol
validation was developed so that manufacturers could produce passive
samplers that reliably assess airborne levels.
Validation Levels
- Full
- Passive monitor has passed all NIOSH protocol validation requirements
for sampling rate, desorption efficiency, humidity effects, reverse
diffusion, storage stability test for reactive compounds whose
stability is suspect, and a factorial study that includes interfering
compounds. This is the most rigorous test possible and includes
all parameters that can affect sampling accuracy (formerly referred
to as Level 5).
- Bi-Level
- A key member of an homologous series has passed Full and all
other members have passed Partial. The validity of this has been
shown by Guild et al. 2 (formerly
referred to as Level 5B).
- Partial
- Passive monitor has passed NIOSH protocol requirements for sampling
rate, desorption efficiency, humidity effects, reverse diffusion,
and storage stability test for reactive compounds. Partial validations
are not recommended for compliance sampling.
- Calculated
- Uptake rate that is calculated from the physical properties of
the analyte and geometry of the sampler. Calculated rates are not
based upon direct laboratory testing of the analyte with the sampler.
Calculated validations are not recommended for compliance sampling.
About OSHA Testing
After extensive testing on the sampling rate variations among diffusive samplers, OSHA has released the following methods that specify diffusive (passive) samplers including SKC Cat. No. 575-002:
- Toluene — Method 111 (1998)
- Tetrachloroethylene and Trichloroethylene — Method 1001 (1999)
- Xylenes and Ethylbenzene — Method 1002 (1999)
- 2-Butanone (MEK) and Hexone (MIBK) — Method 1004 (2000)
- Benzene — Method 1005 (2002)
- Butyl acetates — Method 1009 (2007)
- Styrene — Method 1014 (2009)
OSHA continues its work on passive method development based on the premise that diffusive samplers are a viable alternative to tube/pump sampling.
Transferable Sorbent Passive Sampler
SKC introduces a 575 Series passive sampler option. The new 579 Series passive
samplers are designed to allow sorbent to be transferred from the sampler
housing into a standard laboratory vial for solvent extraction and analysis.
This design provides convenience for laboratories using gas chromatographs
with auto samplers. The sampler housing can be reused several times to reduce
cost. A sorbent transfer funnel is available.
Passive Sampler for Styrene
The 575-006 Passive Sampler for styrene meets the specifications of new OSHA
Method 1014. The sampler contains 500 mg of tert-butyl catechol-treated
Anasorb 747 sorbent. At an uptake rate of 13.55 ml/min, the badge samples
styrene for 15-minute Ceiling or 8-hour TWA sampling times (not suitable
for 5-minute peak samples)
Passive Sampler Ordering Information
Complete instructions are included with each
sampler package
| Description |
Sorbent
(Amount) |
Qty. |
Cat. No. |
| Passive Sampler for Organic Vapor |
Charcoal
(350 mg) |
5 |
575-001 |
| 25 |
575-001A |
| 100 |
575-001B |
| 500 |
575-001C |
| Passive Sampler for Organic Vapor |
Transferable Sorbent
Charcoal
(350 mg) |
5 |
579-001 |
| Passive Sampler for Organic Vapor |
Anasorb® 747
(500 mg) |
5 |
575-002 |
| 25 |
575-002A |
| 100 |
575-002B |
| 500 |
575-002C |
| Passive Sampler for Organic Vapor |
Transferable Sorbent
Anasorb 747
(500 mg) |
5 |
579-002 |
| Passive Sampler for Organic Vapor |
Anasorb® 727
(300 mg) |
5 |
575-003 |
| Passive Sampler for Ethylene Oxide |
Anasorb 747 coated with Hydrobromic
acid
(500 mg) |
5 |
575-005 |
| 25 |
575-005A |
| 100 |
575-005C |
| Passive Sampler for Styrene |
Anasorb 747 coated with
tert-Butyl catechol
(500 mg) |
5 |
575-006 |
Accessories/Replacement parts |
| Transfer Funnel for 579 Series Samplers |
|
ea |
579-010 |
| Replacement Sorbent for 579 Series Samplers, cleaned
and purged, in vial |
Charcoal
(350 mg) |
pk/5 |
579-011 |
| Replacement Sorbent for 579 Series Samplers, cleaned
and purged, in vial |
Anasorb 747
(500 mg) |
pk/5 |
579-012 |
See the Passive
Sampling Guide for sampling rates.
Passive Sampling Guide
575
Series Passive Sampler Operating Instructions (PDF)
575
Series Passive Sampler Analysis Instructions (PDF)
575-006
Passive Sampler for Styrene Operating Instructions (PDF)
Secondary
Diffusion Barrier for ULTRA and 575 Series Passive Samplers Operating
Instructions (PDF)
579
Series Passive Sampler Operating Instructions (PDF)
579
Series Passive Sampler Analysis Instructions (PDF)
Passive Sampler Research Reports
Passive Samplers Meet CEN 838 Diffusive Sampler
Evaluation Protocols
Contact
me about the 575 Series Passive Samplers
List of Laboratories for Analyzing
575 Passive Samplers
Monitor Pasivo para
Vapores Orgánicos Español Folleto
575 Series Passive Samplers Specified in OSHA Diffusive Methods
OSHA specifies SKC 575 Series diffusive (passive) samplers as a
viable alternative to active sampling in six OSHA diffusive methods.
OSHA continues its work on diffusive method development.
OSHA
Method 111 for Toluene
OSHA
Method 1001 for Tetrachloroethylene and Trichlorethylene
OSHA
Method 1002 for Xylenes and Ethylbenzene
OSHA
Method 1004 for 2-Butanone (MEK) and Hexone (MIBK)
OSHA
Method 1005 for Benzene
OSHA
Method 1009 for Butyl Acetates
OSHA
Method 1014 for Styrene
AIHCE 2002 Presentations
For a listing of laboratories in the U.S. and Canada that analyze Passive Samplers,
see the 575 Series Passive
Samplers Analytical
Laboratories Reference List.
Custom Passive Samplers Available
For specific applications, SKC will manufacture
samplers to meet your specific requirements. Download the Custom Passive Sampler
Order Form in PDF format. Complete
the
form and fax it to your SKC representative or contact
your SKC representative or call the SKC Sales
Department at 724-941-9701 for more information.
Custom Passive
Sampler Order
Form (PDF)
References
- 1.
- Cassinelli, M.E., Hull, R.D., Crable, J.V. and Teass, A.W., "Diffusive
Sampling: An Alternative to Workplace Air Monitoring," A. Berlin, R.H. Brown
and K.J. Saunders (Royal Society of Chemistry, London) (eds.), NIOSH Protocol
for the Evaluation of Passive Monitors, 1987, pp 190-202.
- 2.
- Guild, L.V., Myrmel, K.H., Myers, G. and Dietrich, D.F., "Bi-Level Passive
Monitor Validation: A Reliable Way of Assuring Sampling Accuracy for a Larger
Number of Related Chemical Hazards" Appl. Occup. Environ. Hyg., Vol
7, No. 5, May 1992, pp. 310-317. Reprints available
from SKC! Email your mailing address to SKC Inc at skcmktg@skcinc.com.
This page was last modified June 17, 2010
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